012–06615A Sodium Ion Selective Electrode
15
Symptom Possible Causes Next Step
“Incorrect Answer” incorrect scaling of semilog paper plot voltage potential on the linear axis.
(but calibration curve On the log axis, be sure concentration
is good) numbers within each decade are increasing
with increasing concentration.
incorrect sign be sure to note sign of millivolt reading
correctly
incorrect standards prepare fresh standards
wrong units used apply correct conversion factor:
1.0X10
-3
M = 23.0 ppm as Na
+1
sample pH too acidic adjust pH with ISA
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